UV and light curing adhesives

Ultraviolet (UV) light curing adhesives, also known as light curing materials (LCM), have become popular within the manufacturing sector due to their rapid curing time and strong bond strength. Light curing adhesives can cure in as little as a second and many formulations can bond dissimilar substrates (materials) and withstand harsh temperatures.
These qualities make UV curing adhesives essential to the manufacturing of items in many industrial markets such as electronics, telecommunications, medical, aerospace, glass, and optical. Unlike traditional adhesives, UV light curing adhesives not only bond materials together but they can also be used to seal and coat products.

Emulsion adhesives

Milky-white dispersions often based on polyvinyl acetate(PVA). Used extensively in the woodworking and packaging industries. Also used with fabrics and fabric-based components, and in engineered products such as loudspeaker cones.

Hot adhesives

Hot adhesives, also known as hot melt adhesives, are simply thermoplastics applied in molten form (in the 65-180 C range) which solidify on cooling to form strong bonds between a wide range of materials. These adhesives are popular for crafts because of their ease of use and the wide range of common materials they can join. A glue gun (shown at right) is one method of applying hot adhesives. The glue gun melts the solid adhesive, then allows the liquid to pass through its barrel onto the material, where it solidifies.

Stress strain graph of thermoplastic material

Paul E. Cope is reputed to have invented thermoplastic glue around 1940 while working for Procter & Gamble as a chemical and packaging engineer. His invention solved a problem with water-based adhesives that were commonly used in packaging at that time. Water-based adhesives often failed in humid climates, causing packages to open and become damaged.

Contact adhesives

Contact adhesives must be applied to both surfaces and allowed some time to dry before the two surfaces are pushed together. Some contact adhesives require as long as 24 hours to dry before the surfaces are to be held together.Once the surfaces are pushed together, the bond forms very quickly.It is usually not necessary to apply pressure for a long time, so there is no need to use clamps.

Natural rubber and polychloroprene (Neoprene) are commonly used contact adhesives. Both of these elastomers undergo strain crystallization. Contact adhesives are used in strong bonds with high sheer-resistance like laminates, such as bonding Formica to a wooden counter, and in footwear, such as attaching an outsole to an upper.

Synthetic adhesives

Elastomers, thermoplastics, Emulsion, and thermosetting adhesives based on polyvinyl acetate, epoxy, polyyurethane, cynoacrylate polymers are examples of synthetic adhesives.

Natural Adhesives

Animal glue in granules

Natural adhesives are made from inorganic mineral sources, or biological sources such as vegetable matter, strach (dextrin), natural resins or from animals e.g.animal glue. They are often referred to as bioadhesives. One example is a simple paste made by cooking flour in water. Animal glues are traditionally used in bookbinding, wood joining, and many other areas but now are largely replaced by synthetic glues. Casein are mainly used in glass bottle labelling. Starch based adhesives are used in corrugated board production and paper sack production, paper tube winding, wall paper adhesives. Another form of natural adhesive is blood albumen (made from protein component of blood), which is used in the plywood industry. Animal glue remains the preferred glue of the luthier.

Pressure sensitive adhesives

Pressure sensitive adhesives (PSA) form a bond by the application of light pressure to marry the adhesive with the adherend. They are designed with a balance between flow and resistance to flow. The bond forms because the adhesive is soft enough to flow (i.e. "wet") the adherend. The bond has strength because the adhesive is hard enough to resist flow when stress is applied to the bond. Once the adhesive and the adherend are in close proximity, molecular interactions, such as Van der Waals forces, become involved in the bond, contributing significantly to its ultimate strength.

PSAs are designed for either permanent or removable applications. Examples of permanent applications include safety labels for power equipment, foil tape for HVAC duct work, automotive interior trim assembly, and sound/vibration damping films. Some high performance permanent PSAs exhibit high adhesion values and can support kilograms of weight per square centimeter of contact area, even at elevated temperature. Permanent PSAs may be initially remova

ble (for example to recover mislabeled goods) and build adhesion to a permanent bond after several hours or days.

Removable adhesives are designed to form a temporary bond, and ideally can be removed after months or years without leaving residue on the adherend. Removable adhesives are used in applications such as surface protection films, masking tapes, bookmark and note papers, price marking labels, promotional graphics materials, and for skin contact (wound care dressings, EKG electrodes, athletic tape, analgesic and transdermal drug patches, etc.). Some removable adhesives are designed to repeatedly stick and unstick. They have low adhesion and generally can not support much weight.

Assuming hydrogen and oxygen are standard weights in this image (as opposed to deuterium oxide) the molecular mass

Pressure sensitive adhesives are manufactured with either a liquid carrier or in 100% solid form. Articles are made from liquid PSAs by coating the adhesive and drying off the solvent or water carrier. They may be further heated to initiate a cross-linking reaction and increase mocular weight.

100% solid PSAs may be low viscosity polymers that are coated and then reacted with radiation to increase molecular weight and form the adhesive; or they may be high viscosity materials that are heated to reduce viscosity enough to allow coating, and then cooled to their final form. Major raw material for PSA´s are acrylate based polymers.

Drying adhesives

These adhesives are a mixture of ingredients (typically polymers) dissolved in a solvent. White glue and rubber cements are members of the drying adhesive family. As the solvent evaporates, the adhesive hardens. Depending on the chemical composition of the adhesive, they will adhere to different materials to greater or lesser degrees. These adhesives are typically weak and are used for household applications.